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Depositordc.contributorMoggach, Stephen
Funderdc.contributor.otherEPSRC - Engineering and Physical Sciences Research Councilen_UK
Date Accessioneddc.date.accessioned2015-12-14T14:07:04Z
Date Availabledc.date.available2016-12-11T05:15:07Z
Citationdc.identifier.citationThe University of Edinburgh School of Chemistry. (2016). Pore Shape Modification of a Microporous Metal-Organic Frame-work Using High Pressure: Accessing a New Phase with Oversized Guest Molecules, [dataset]. https://doi.org/10.7488/ds/371.en
Persistent Identifierdc.identifier.urihttp://hdl.handle.net/10283/942
Persistent Identifierdc.identifier.urihttps://doi.org/10.7488/ds/371
Dataset Description (abstract)dc.description.abstractPressures up to 0.8 GPa have been used to squeeze a range of sterically “oversized” C5–C8 alkane guest molecules into the cavities of a small-pore Sc-based metal–organic framework. Guest inclusion causes a pronounced reorientation of the aromatic rings of one-third of the terephthalate linkers, which act as “torsion springs”, resulting in a fully reversible change in the local pore structure. The study demonstrates how pressure-induced guest uptake can be used to investigate framework flexibility relevant to “breathing” behavior and to understand the uptake of guest molecules in MOFs relevant to hydrocarbon separation.en
Languagedc.language.isoengen_UK
Publisherdc.publisherThe University of Edinburgh School of Chemistryen_UK
Relation (Is Referenced By)dc.relation.isreferencedbyhttps://doi.org/10.1021/acs.chemmater.5b02891en_UK
Relation (Is Referenced By)dc.relation.isreferencedbyMcKellar SC; Sotelo J; Greenaway A; Mowat JPS; Kvam O; Morrison CA; Wright PA; Moggach SA. (2015) "Pore Shape Modification of a Microporous Metal-Organic Frame-work Using High Pressure: Accessing a New Phase with Oversized Guest Molecules". DOI: 10.1021/acs.chemmater.5b02891
Rightsdc.rightsCreative Commons Attribution 4.0 International Public Licenseen
Titledc.titlePore Shape Modification of a Microporous Metal-Organic Frame-work Using High Pressure: Accessing a New Phase with Oversized Guest Moleculesen_UK
Typedc.typedataseten_UK

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