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Depositordc.contributorShaver, Michael
Funderdc.contributor.otherEPSRC - Engineering and Physical Sciences Research Councilen_UK
Spatial Coveragedc.coverage.spatialUKen
Spatial Coveragedc.coverage.spatialUNITED KINGDOMen
Data Creatordc.creatorLake, Ben
Date Accessioneddc.date.accessioned2015-07-07T16:37:08Z
Date Availabledc.date.available2016-01-07T05:15:16Z
Citationdc.identifier.citationLake, Ben. (2016). Macromolecules 2015 "A Synthetic and Multispectroscopic Speciation Analysis of Controlled Radical Polymerization Mediated by Amine–Bis(phenolate)iron Complexes" - EPSRC EPSRC EP/M000842/1, [dataset]. University of Edinburgh. https://doi.org/10.7488/ds/281.en
Persistent Identifierdc.identifier.urihttp://hdl.handle.net/10283/823
Persistent Identifierdc.identifier.urihttps://doi.org/10.7488/ds/281
Dataset Description (abstract)dc.description.abstractThe mechanism of reversible-deactivation radical polymerization (RDRP) mediated by chloro-substituted amine–bis(phenolate)iron complexes was studied via a combination of Mössbauer, EPR, NMR, and online Vis/NIR spectroscopy. It was found that styrene polymerization operates via an atom-transfer radical polymerization (ATRP) mechanism when alkyl halide is present, whereas an interplay between ATRP and organometallic-mediated radical polymerization (OMRP) equilibria occurs during MMA polymerization. The preparation of the amine–bis(phenolate)iron(II) complex, [O2NN′]FeII, allowed polymerizations to be performed under an OMRP-only regime free of alkyl halide that yields dispersities as low as 1.29 for MMA polymerization.en_UK
Dataset Description (TOC)dc.description.tableofcontentsZIP file containing Gel-permeation Chromatographs; compound spectroscopic information (NMR); X-ray crystallography cif files; in industry standard formats.en_UK
Languagedc.language.isoengen_UK
Publisherdc.publisherUniversity of Edinburghen_UK
Relation (Is Referenced By)dc.relation.isreferencedby10.1021/acs.macromol.5b01175en_UK
Relation (Is Referenced By)dc.relation.isreferencedbySchroeder H, Lake BRM, Demeshko S, Shaver MP, Bruback M (2 Jul 2015) "A Synthetic and Multispectroscopic Speciation Analysis of Controlled Radical Polymerization Mediated by Amine–Bis(phenolate)iron Complexes" Macromoleculesen_UK
Rightsdc.rightsCreative Commons Attribution 4.0 International Public Licenseen
Titledc.titleMacromolecules 2015 "A Synthetic and Multispectroscopic Speciation Analysis of Controlled Radical Polymerization Mediated by Amine–Bis(phenolate)iron Complexes" - EPSRC EPSRC EP/M000842/1en_UK
Typedc.typedataseten_UK

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